Browsing by Author "Chen, Ying"
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Item Open Access Mitigation of platinum depletion in platinum diffused single phase bond coat on CMSX-4 superalloy(MDPI, 2021-05-31) Bai, Mingwen; Chen, Ying; Sun, Yongle; Xiao, PingPt-diffused bond coat with a mixture of γ/γ’ phase has just been developed in the recent decades as a cheaper alternative to the Pt-enriched β-phase Aluminide bond coat that contains a higher content of Al. However, concerns are raised on the inevitable depletion of Pt near the coating interface that may endanger the component after long-term service. In this study, modified Pt-diffused bond coats with a single phase (γ or γ’) were made by applying selective etching on CMSX-4 single crystal superalloys prior to the electroplating of Pt. The single-phase bond coats show distinctive diffusion behaviour in comparison with the conventional γ/γ’ bond coat. Surprisingly, Pt remains more stable in the γ’-phase bond coat with significantly less depletion after diffusion, which implies a potential in saving a considerable amount of Pt. On the other hand, however, the depletion of Pt is more severe in the γ-phase bond coat. The mechanism that governs the diffusion behavior of Pt in the γ and γ’-phase was also discussed that mainly concerns with thermodynamic and kinetic factors.Item Open Access Strain tolerance evolution of EB-PVD TBCs after thermal exposure or CMAS attack(Elsevier, 2023-08-28) Gao, Zhaohe; Zhang, Xun; Chen, Ying; Chalk, Christine; Nicholls, John; Brewster, Gyaneshwara; Xiao, PingThe microstructural evolution and Young’s modulus evolution of EB-PVD TBCs upon thermal exposure and separately after CaO-MgO-Al2O3-SiO2 (CMAS) attack have been compared and investigated. Moduli measured by four methods all show an increase due to sintering whereas their rates of increase are different. On finer scale (i.e. nano indentation), modulus increases from 87.3 GPa in as-deposited coatings to 198 GPa after sintering at 1400 °C for 100 h. While on global scale, the modulus increases from below 10 GPa to153 GPa after identical exposure. For the CMAS attacked TBCs at 1300 °C for 0.5 h, modulus values acquired by different methods are much closer. The effect of sintering and CMAS infiltration on coating’s structural integrity is discussed in terms of elastic strain energy available for driving edge delamination. The energy release rate of CMAS attacked TBCs at 1300 °C for 0.5 h is ∼1200 J/m2, which is equivalent to that of TBCs exposed at 1400 °C for 250 h (no CMAS).