Browsing by Author "Hardy, M. C."

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    Comparison of Performance of NiCr2O4 and Cr2O3 Formed on the Ni-Based Superalloy RR1000 Under Corrosive Conditions
    (Springer, 2024) Gray, S.; Mphahlele, M.; Collins, D. M.; Jackson, C.; Hardy, M. C.; Taylor, M. P.
    Samples of the Ni-based superalloy, RR1000, were exposed to 98% Na2SO4/2% NaCl salts at 700 °C with a flux of 1.5 µg cm−2 h−1 in flowing air + 300 ppm SO2 for a total of 250 h. Three pre-exposure conditions were studied: a bare reference alloy; fast heating to the test temperature followed by a 100 h hold; heating at a rate of 5 °C min−1 to the test temperature following by a 100 h hold. The surface oxide formed under the latter two conditions were Cr2O3 or NiCr2O4, respectively. The results show corrosion pit formation on the surface of the base, reference sample, and no pits present on the sample with the preformed Cr2O3. Some protection was found for the sample heated at 5 °C min−1 with a delay in the progression to accelerated corrosion attack. Additional testing under moisture containing air was also conducted. This showed no obvious difference in surface oxide morphology under the two tested heating rates for the short-term exposures examined but a difference was noted to be dependent on the moisture content of the air.
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    Effects of oxidation and hot corrosion in a nickel disc alloy
    (2008-12-31T00:00:00Z) Encinas-Oropesa, Adriana; Drew, G. L.; Hardy, M. C.; Leggett, A. J.; Nicholls, John R.; Simms, Nigel J.
    This paper describes work to study oxidation and hot corrosion damage in nickel disc alloy RR1000. Oxidation damage has been characterised via mass change data from thermogravimetric analyses at temperatures from 700 to 800 ºC and cyclic oxidation testing at 700 and 750 ºC. Thin oxide scales rich in Cr and Ti have been found to grow in a parabolic dependence with time. Oxidation rate constants have been correlated with temperature using an Arrhenius equation. Through the use of simplifying assumptions, mass change data have been converted to oxide thickness values. These values have been compared with observed values of oxide scale and the depth of near-surface damage, which have been measured using focused ion beam (FIB) microscopy. Hot corrosion of RR1000 has been studied in the laboratory by ‘deposit' recoat experiments at 700ºC. In these tests, samples were coated with deposits of Na2SO4/NaCl salt in a gas stream of air-300 vpm SO2. Corrosion damage has been quantified by dimensional metrology of samples before and after exposure. This enabled metal losses, i.e. the depth of corrosion pits, to be determined. Distributions of metal loss data were then generated to produce median damage values and exceedance cumulative probabilities. Finally, the effect of contaminants on the hot corrosion resistance of RR1000 has also been evaluated.