Browsing by Author "Rizvi, Syed Haider Mehdi"

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    Evaluation of the influence of dissolved nitrates on corrosion behaviour of ship structural steel exposed to seawater environment
    (Elsevier, 2024-02-29) Abbas, Muntazir; Rizvi, Syed Haider Mehdi; Sarfraz, Shoaib; Raza, Asif; Khan, Asif; Loya, Adil; Najib, Antash
    Corrosion rates in marine structural steels differ significantly with the varying compositions of seawater particularly near harbours or coastal regions primarily due to the presence of untreated chemically active species from various sources. The reviewed literature reports accelerated steel corrosion losses in coastal seawater exposure conditions, which has widely been attributed to the presence of aggressive chemical compounds e.g., dissolved inorganic nitrogenous (DINs) compounds, sulphur containing compounds, in combination with various other environmental factors and their interdependent complex relationships. This paper aims to investigate the influence of nitrates, a DIN compound, on the corrosion behaviour of a low carbon ship structural steel, by exposing surface the cleaned coupons to an artificial seawater solution in a controlled laboratory environment. The uniform and localised corrosion damages were measured on steel coupons by using the standard weight loss and the dimensional metrology methods. A significant increase in corrosion losses was observed on coupons exposed to the nitrate-added artificial seawater than those exposed to similar seawater compositions with no additional nitrate content. Elemental compositions of corrosion deposits and corrosion morphologies investigated using various analytical tools such as SEM, EDS and Raman scattering techniques have shown different types of corrosion products in both exposure conditions.
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    A new approach for quantification of corrosion losses on steels exposed to an artificial seawater environment
    (Taylor & Francis, 2023-03-13) Abbas, Muntazir; Simms, Nigel; Rizvi, Syed Haider Mehdi
    The selection methodology for thickness loss measurement is very important to determine the extent of corrosion damage, as well as in formulation of corrosion prediction models and inspection/maintenance plans for offshore structures. This paper introduces a more accurate corrosion measurement technique, based on the pre-exposure dimensional metrology and post-exposure optical microscopy/image analysis on the cross-sections of steel samples. During this corrosion test, the surface grinded and uncoated steel samples were submerged vertically in an artificial seawater solution, for a duration of up to a maximum of 365 days. The corrosion damage experienced on the steel samples means that the dimensional metrology can be more accurate, and useful approach to measure both uniform and localised corrosion losses simultaneously than the conventional average mass loss method.