Browsing by Author "Zhang, Qibo"
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Item Open Access Carbon-based polymer nanocomposite for high-performance energy storage applications(MDPI, 2020-02-26) Siwal, Samarjeet Singh; Zhang, Qibo; Devi, Nishu; Thakur, Vijay KumarIn recent years, numerous discoveries and investigations have been remarked for the development of carbon-based polymer nanocomposites. Carbon-based materials and their composites hold encouraging employment in a broad array of fields, for example, energy storage devices, fuel cells, membranes sensors, actuators, and electromagnetic shielding. Carbon and its derivatives exhibit some remarkable features such as high conductivity, high surface area, excellent chemical endurance, and good mechanical durability. On the other hand, characteristics such as docility, lower price, and high environmental resistance are some of the unique properties of conducting polymers (CPs). To enhance the properties and performance, polymeric electrode materials can be modified suitably by metal oxides and carbon materials resulting in a composite that helps in the collection and accumulation of charges due to large surface area. The carbon-polymer nanocomposites assist in overcoming the difficulties arising in achieving the high performance of polymeric compounds and deliver high-performance composites that can be used in electrochemical energy storage devices. Carbon-based polymer nanocomposites have both advantages and disadvantages, so in this review, attempts are made to understand their synergistic behavior and resulting performance. The three electrochemical energy storage systems and the type of electrode materials used for them have been studied here in this article and some aspects for example morphology, exterior area, temperature, and approaches have been observed to influence the activity of electrochemical methods. This review article evaluates and compiles reported data to present a significant and extensive summary of the state of the art.Item Open Access Energy production from steam gasification processes and parameters that contemplate in biomass gasifier - a review(Elsevier, 2019-11-26) Siwal, Samarjeet Singh; Zhang, Qibo; Sun, Changbin; Thakur, Sourbh; Gupta, Vijai Kumar; Thakur, Vijay KumarThe transformation of biomass using steam gasification is a chemical route to facilitate changes in organic or residue supported carbonaceous substances addicted to carbon mono-oxide, hydrogen including carbon-di-oxide, etc. However, to commercialize the method of steam gasification, the hurdles persist during the gasification as well as downstream processing. This article delivers a summary of the different approaches that are described in the previous studies to achieve H2 refinement and adaptation within the gasifier system. These include advanced aspects in the research and development of biomass gasification (alike advancements under the gasification operation). The upshot of diverse operating conditions like steam flow rate, operating temperature, moisture content, gasifier agents, residence time, biomass to air, steam to biomass, equivalence ratio, etc. towards the execution of biomass gasifier. This review accomplishes that the interdependence of several issues must be considered in point to optimise the producer gas.Item Open Access Graphitic carbon nitride doped copper–manganese alloy as high–performance electrode material in supercapacitor for energy storage(MDPI, 2019-12-18) Siwal, Samarjeet Singh; Zhang, Qibo; Sun, Changbin; Thakur, Vijay KumarHere, we report the synthesis of copper–manganese alloy (CuMnO2) using graphitic carbon nitride (gCN) as a novel support material. The successful formation of CuMnO2-gCN was confirmed through spectroscopic, optical, and other characterization techniques. We have applied this catalyst as the energy storage material in the alkaline media and it has shown good catalytic behavior in supercapacitor applications. The CuMnO2-gCN demonstrates outstanding electrocapacitive performance, having high capacitance (817.85 A·g−1) and well-cycling stability (1000 cycles) when used as a working electrode material for supercapacitor applications. For comparison, we have also used the gCN and Cu2O-gCN for supercapacitor applications. This study proposes a simple path for the extensive construction of self-attaining double metal alloy with control size and uniformity in high-performance energy-storing materialsItem Open Access Recent advances in bio-electrochemical system analysis in biorefineries(Elsevier, 2021-07-02) Siwal, Samarjeet Singh; Zhang, Qibo; Saini, Adesh Kumar; Gupta, Vijai Kumar; Roberts, Dave; Saini, Vipin; Coulon, Frederic; Pareek, Bhawna; Thakur, Vijay KumarConcerns around acquiring the appropriate resources toward a growing world population have emphasized the significance of crucial connections between food, energy, and water devices, as described within the food-energy-water nexus theory. Advanced biorefineries provide second-generation biofuels and added-value chemicals through food products have affected these nexus sources. We combine various conversion technologies and expected options to look further for cost-effective technologies that maximize the value of resource use and reuse and minimize the amount of resource needed and environmental impacts. In this review article, our central focus is on structure and application, the outline of food-energy-water (FEW) nexus in biorefineries and bio-electrochemical system (BES) and looking into the energy-efficient and value-added product recovery. In addition, based on BES analysis for energy efficiency and valuable product recoveries such as hydrogen evaluation, acetate, recovery of heavy metals, nutrient’s recovery has been discussed under this article. Additionally, we focused on wastewater processing methods, novel electrode materials used in BES, BESs-based desalination and wastewater treatment, recent BES architecture and designs, genetic engineering for enhanced productivity, and valuable materials production surfactants and hydrogen peroxide. Finally, we concluded the topic by discussing the remediation of soil contamination, photosynthetic & microfluidic BES systems, possibilities of employing CO2, including prospects and challenges.