Zeng, Xie-RongWenwu, JinLi, HejunSaikumar, InguvaZhang, QiShaozhong, ZengGuozhong, XuZou, Jizhao2020-01-202020-01-202019-12-20Zeng X, Jin W, Li H, et al., (2019) Al-based MOF derived self-assembled carbon nanosheets as innovative anodes for Li-and Na-ion batteries, Nanotechnology, Volume 31, Issue 15, 2020, Article number 1556020957-4484https://doi.org/10.1088/1361-6528/ab647bhttps://dspace.lib.cranfield.ac.uk/handle/1826/14963Functional modification and structural design of carbon electrode materials are considered as a cost-effective method to improve their electrochemical performance. In this study, a solvothermal method is applied to realize self-assembly of the metal-organic framework. After simple carbonization and acid treatment, carbon nanosheets with 2D adjustable defective sub-units are successfully prepared for the first time. It is found that carbonization temperature has a significant effect on the carbon skeleton structure. The optimal nanostructures with large specific surface area and appropriate pore size distribution make self-assembled carbon nanosheets having excellent Li/Na- ion storage properties. In addition, the adjustable carbon skeleton structure can effectively avoid irreversible damage when charge-discharge cycles. For Li-ion batteries, a specific capacity of 825 mAh g−1 is achieved after 100 cycles at 0.1 C, while for Na-ion batteries a specific capacity of 193 mAh g−1 is observed after 100 cycles at 0.5 C. Moreover, for Na-ion batteries, even at a high rate of 5 C the material delivers a specific capacity of 109.5 mAh g−1 after 3500 cycles.enAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Porous carbon nanosheetsnanostructure2D-MOFLi-ionNa-ionArticle