Browsing by Author "Gobey, Katherine"

Now showing 1 - 2 of 2
  • Thumbnail Image
    ItemOpen Access
    Investigation of an Atmospheric Pressure Plasma device for reduction of water use in sustainable cleaning of concentrating solar power mirrors
    (Cranfield University, 2023-06) Gobey, Katherine; King, Peter; Sansom, Chris
    Concentrating Solar Power (CSP) is a method of renewable electricity generation that uses large areas of mirrors, that reflect and focus the sun’s energy onto a receiver which is then used to heat water to power a conventional steam turbine, generating electricity. These plants are typically located in areas with consistently high levels of sunlight which are typically arid desert areas where sand and dust is deposited onto the mirrors, reducing their reflectivity and thus the plant’s output. Conventional mirror washing consumes huge quantities of water, which is costly and incurs ethical and environmental concerns in areas already experiencing water scarcity. This work investigates the use of an atmospheric pressure plasma to induce a super-hydrophilic surface on the soiled mirrors which are then able to be cleaned with significantly lower quantities of water. Characterisation of the plasma torch is conducted, and surface energy modification effects investigated with regards to water spreading, evaporation, and travel. For cleaning trials, solar type mirrors were artificially soiled with sand gathered from a CSP plant, then plasma processed before being conventionally washed with water. Mirrors that were subject to soiling were successfully washed, as determined by reflectance measurements, with up to 87.5% less water than mirrors exposed to the same artificial soiling procedure but without plasma processing prior to washing. Plasma processed samples also exhibited self-cleaning properties when subject to condensation trials, mimicking overnight dew formation. There was no observed effect in either reduction or exacerbation of subsequent resoiling of plasma processed samples. Fundamental processes behind these effects are discussed and the application and implication of the work are considered.
  • Thumbnail Image
    ItemOpen Access
    The recovery of high value metals from spent lithium-ion batteries.
    (2018-08) Gobey, Katherine; Zhang, Qi
    Much of the modern technological world in which we live is dependent on reliable energy storage in the form of batteries, from small goods such as mobile phones, to backup power systems, and everything in between. Battery use is expected to increase considerably in the near future, and as such so will battery waste, resulting in a need for efficient, economical, and environmentally friendly processing and recycling of waste batteries and their components. This project set out to investigate a new potential method of separation of cobalt and lithium from Lithium-Ion Batteries (LIB), using sodium alginate, an anionic polysaccharide already widely harvested from multiple species of seaweed, that forms an insoluble cross link polymer with divalent cation Co²⁺, thus allowing cobalt to be easily extracted and separated from the lithium in the solution. It was found that, following creation of a cobalt ion solution using water, nitric acid, and reductant hydrogen peroxide, sodium alginate solution readily formed insoluble cobalt alginate, which can then be easily removed from the solution, allowing separation of lithium and cobalt in a simple step. With fresh sodium alginate beads added in multiple runs of 2 hours up to 93.4% of cobalt by mass was removed from the solution. Alginate added and left for up to 72 hours produced lower yields of up to 79.82% removal.