Browsing by Author "Green, Kevin"
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Item Open Access Biological carbon dioxide utilisation in food waste anaerobic digesters(Elsevier, 2015-06-09) Bajón Fernández, Yadira; Green, Kevin; Schuler, K.; Soares, Ana; Vale, Peter C. J.; Alibardi, Luca; Cartmell, EliseCarbon dioxide (CO2) enrichment of anaerobic digesters (AD) was previously identified as a potential on-site carbon revalorisation strategy. This study addresses the lack of studies investigating this concept in up-scaled units and the need to understand the mechanisms of exogenous CO2 utilisation. Two pilot-scale ADs treating food waste were monitored for 225 days, with the test unit being periodically injected with CO2 using a bubble column. The test AD maintained a CH4 production rate of 0.56 ± 0.13 m3 CH4·(kg VSfed d)−1 and a CH4 concentration in biogas of 68% even when dissolved CO2 levels were increased by a 3 fold over the control unit. An additional uptake of 0.55 kg of exogenous CO2 was achieved in the test AD during the trial period. A 2.5 fold increase in hydrogen (H2) concentration was observed and attributed to CO2 dissolution and to an alteration of the acidogenesis and acetogenesis pathways. A hypothesis for conversion of exogenous CO2 has been proposed, which requires validation by microbial community analysis.Item Open Access Performance and stability of sewage sludge digestion under CO2 enrichment: a pilot study(Elsevier, 2017-08-16) Alibardi, Luca; Green, Kevin; Favaro, Lorenzo; Vale, Peter C. J. ; Soares, Ana; Cartmell, Elise; Bajón Fernández, YadiraCarbon dioxide (CO2) injection in anaerobic digestion has recently been proposed as an interesting possibility to boost methane (CH4) recovery from sludge and organic waste by converting a greenhouse gas into a renewable resource. This research assessed the effects of exogenous CO2 injection on performance and process stability of single-phase continuous anaerobic digesters. Two pilot scale reactors treating sewage sludge were operated for 130 days. One reactor was periodically injected with CO2 while the other acted as control. Two injection frequencies and injection devices were tested. The results indicated that CO2 enrichment allowed an increase in CH4 production of ca. 12%, with a CH4 production rate of 371 ± 100 L/(kgVSfed⋅d) and a CH4 concentration of ca. 60% when dissolved CO2 levels inside the test reactor were increased up to 1.9-fold. Results also indicated an improvement in process resilience to temporary overloads and no impacts on stability parameters.