Browsing by Author "Ochs, Pascal"

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    Ammonia removal from thermal hydrolysis dewatering liquors via three different deammonification technologies
    (Elsevier, 2020-10-06) Ochs, Pascal; Martin, Benjamin D.; Germain, Eve; Stephenson, Tom; van Loosdrecht, Mark C. M.; Soares, Ana
    The benefits of deammonification to remove nitrogen from sidestreams, i.e., sludge dewatering liquors, in municipal wastewater treatment plants are well accepted. The ammonia removal from dewatering liquors originated from thermal hydrolysis/anaerobic digestion (THP/AD) are deemed challenging. Many different commercial technologies have been applied to remove ammonia from sidestreams, varying in reactor design, biomass growth form and instrumentation and control strategy. Four technologies were tested (a deammonification suspended sludge sequencing batch reactor (S-SBR), a deammonification moving bed biofilm reactor (MEDIA), a deammonification granular sludge sequencing batch reactor (G-SBR), and a nitrification suspended sludge sequencing batch reactor (N-SBR)). All technologies relied on distinct control strategies that actuated on the feed flow leading to a range of different ammonia loading rates. Periods of poor performance were displayed by all technologies and related to imbalances in the chain of deammonification reactions subsequently effecting both load and removal. The S-SBR was most robust, not presenting these imbalances. The S-SBR and G-SBR presented the highest nitrogen removal rates (NRR) of 0.58 and 0.56 kg N m−3 d−1, respectively. The MEDIA and the N-SBR presented an NRR of 0.17 and 0.07 kg N m−3 d−1, respectively. This study demonstrated stable ammonia removal from THP/AD dewatering liquors and did not observe toxicity in the nitrogen removal technologies tested. It was identified that instrumentation and control strategy was the main contributor that enabled higher stability and NRR. Overall, this study provides support in selecting a suitable biological nitrogen removal technology for the treatment of sludge dewatering liquors from THP/AD
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    Evaluation of a full-scale suspended sludge deammonification technology coupled with an hydrocyclone to treat thermal hydrolysis dewatering liquors
    (MDPI, 2021-02-01) Ochs, Pascal; Martin, Benjamin D.; Germain, Eve; Wu, Zhuoying; Lee, Po-Heng; Stephenson, Tom; van Loosdrecht, Mark C. M.; Soares, Ana
    Suspended sludge deammonification technologies are frequently applied for sidestream ammonia removal from dewatering liquors resulting from a thermal hydrolysis anaerobic digestion (THP/AD) process. This study aimed at optimizing the operation, evaluate the performance and stability of a full-scale suspended sludge continuous stirred tank reactor (S-CSTR) with a hydrocyclone for anaerobic ammonia oxidizing bacteria (AMX) biomass separation. The S-CSTR operated at a range of nitrogen loading rates of 0.08–0.39 kg N m−3 d−1 displaying nitrogen removal efficiencies of 75–89%. The hydrocyclone was responsible for retaining 56–83% of the AMX biomass and the washout of ammonia oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) was two times greater than AMX. The solid retention time (SRT) impacted on NOB washout, that ranged from 0.02–0.07 d−1. Additionally, it was demonstrated that an SRT of 11–13 d was adequate to wash-out NOB. Microbiome analysis revealed a higher AMX abundance (Candidatus scalindua) in the reactor through the action of the hydrocyclone. Overall, this study established the optimal operational envelope for deammonification from THP/AD dewatering liquors and the role of the hydrocyclone towards maintaining AMX in the S-CSTR and hence obtain process stability.
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    Raw and analysed data for four ammonia removal technologies treating THP/AD dewatering liquors
    (Cranfield University, 2020-10-09 09:06) Ochs, Pascal; Soares, Ana; Stephenson, Tom; D. Martin, Benjamin; Germain, Eve; van Loosdrecht, M.C.M. (Mark)
    The data set contains influent, effluent and performance data for the paper "Ammonia removal from thermal hydrolysis dewatering liquors via three different deammonification technologies". The data is stored in an excel spreadsheet including raw data, cleaned up data and details to analysis.
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    Techno-economic analysis of sidestream ammonia removal technologies: biological options versus thermal stripping
    (Elsevier, 2022-11-22) Ochs, Pascal; Martin, Ben; Germain-Cripps, Eve; Stephenson, Tom; van Loosdrecht, Mark; Soares, Ana
    Over the past twenty years, various commercial technologies have been deployed to remove ammonia (NH4–N) from anaerobic digestion (AD) liquors. In recent years many anaerobic digesters have been upgraded to include a pre-treatment, such as the thermal hydrolysis process (THP), to produce more biogas, increasing NH4–N concentrations in the liquors are costly to treat. This study provides a comparative techno-economic assessment of sidestream technologies to remove NH4–N from conventional AD and THP/AD dewatering liquors: a deammonification continuous stirred tank reactor (PNA), a nitrification/denitrification sequencing batch reactor (SBR) and thermal ammonia stripping process with an ammonia scrubber (STRIP). The SBR and PNA were based on full-scale data, whereas the STRIP was designed using a computational approach to achieve NH4–N removals of 90–95%. The PNA presented the lowest whole-life cost (WLC) over 40 years, with £7.7 M, while the STRIP had a WLC of £43.9 M. This study identified that THP dewatering liquors, and thus a higher ammonia load, can lead to a 1.5–3.0 times increase in operational expenditure with the PNA and the SBR. Furthermore, this study highlighted that deammonification is a capable and cost-effective nitrogen removal technology. Processes like the STRIP respond to current pressures faced by the water industry on ammonia recovery together with targets to reduce nitrous oxide emissions. Nevertheless, ammonia striping-based processes must further be demonstrated in WWTPs and WLC reduced to grant their wide implementation and replace existing technologies.