Browsing by Author "Orisawayi, Abimbola Oluwatayo"

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    Development and characterisation of integrated wet-spun alginate-Moringa oleifera composite fibers for potential water purification
    (Elsevier, 2025-03) Orisawayi, Abimbola Oluwatayo; Koziol, Krzysztof; Rahatekar, Sameer S
    Ensuring access to safe drinking water requires effective materials and technologies to treat contaminated water. In this study, we developed sodium alginate fibre (SAlgF) and their composite fibres functionalised with pulverised Moringa oleifera (MoP) at concentrations of 0.5 %, 1 %, 4 %, and 8 % using the wet-spinning technique. Both SAlgF and MoP are biodegradable, offering eco-friendly alternatives to synthetic polymers in line with green manufacturing. The results showed significant improvements in the mechanical properties, with the 1 % MoP composite fibre exhibiting 6 times the strength of pure SAlgF in terms of ultimate tensile strength (UTS) and Young's modulus (YM). X-ray Diffraction (XRD) analysis revealed enhanced fibres interactions, while Fourier Transform Infrared Spectroscopy (FTIR) and Thermogravimetric Analysis (TGA) confirmed the successful incorporation of MoP into the alginate matrix and improved thermal stability. Furthermore, the result obtained from the Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDX) indicated morphological changes and the uptake of heavy metal ions when immersed into solutions containing Cu²⁺, Ni²⁺, and Cd²⁺. These findings demonstrate the potential of MoP-modified composite fibres for sustainable and cost-effective water treatment applications, particularly in developing countries.
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    Development of hybrid electrospun alginate-pulverized moringa composites
    (Royal Society of Chemistry, 2024-03-12) Orisawayi, Abimbola Oluwatayo; Koziol, Krzysztof K. K.; Hao, Shuai; Tiwari, Shivam; Rahatekar, Sameer S.
    The consideration of biopolymers with natural products offers promising and effective materials with intrinsic and extrinsic properties that are utilized in several applications. Electrospinning is a method known for its unique and efficient performance in developing polymer-based nanofibers with tunable and diverse properties presented as good surface area, morphology, porosity, and fiber diameters during fabrication. In this work, we have developed an electrospun sodium alginate (SA) incorporated with pulverized Moringa oleifera seed powder (PMO) as a potential natural biosorbent material for water treatment applications. The developed fibers when observed using a scanning electron microscope (SEM), presented pure sodium alginate with smooth fiber (SAF) characteristics of an average diameter of about 515.09 nm (±114.33). Addition of pulverized Moringa oleifera at 0.5%, 2%, 4%, 6%, and 8% (w/w) reduces the fiber diameter to an average of about 240 nm with a few spindle-like pulverized Moringa oleifera particles beads of 300 nm (±77.97) 0.5% particle size and 110 nm (±32.19) with the clear observation of rougher spindle-like pulverized Moringa oleifera particle beads of 680 nm (±131.77) at 8% of alginate/Moringa oleifera fiber (AMF). The results from the rheology presented characteristic shear-thinning or pseudoplastic behaviour with a decline in viscosity, with characteristic behaviour as the shear rate increases, indicative of an ideal polymer solution suitable for the spinning process. Fourier transform infrared spectroscopy (FT-IR) shows the presence of amine and amide functional groups are prevalent on the alginate-impregnated moringa with water stability nanofibers and thermogravimetric analysis (TGA) with change in degradation properties in a clear indication and successful incorporation of the Moringa oleifera in the electrospun fiber. The key findings from this study position nanofibers as sustainable composites fiber for potential applications in water treatment, especifically heavy metal adsorption.