Browsing by Author "Siwal, Samarjeet Singh"

Now showing 1 - 6 of 6
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    Carbon-based polymer nanocomposite for high-performance energy storage applications
    (MDPI, 2020-02-26) Siwal, Samarjeet Singh; Zhang, Qibo; Devi, Nishu; Thakur, Vijay Kumar
    In recent years, numerous discoveries and investigations have been remarked for the development of carbon-based polymer nanocomposites. Carbon-based materials and their composites hold encouraging employment in a broad array of fields, for example, energy storage devices, fuel cells, membranes sensors, actuators, and electromagnetic shielding. Carbon and its derivatives exhibit some remarkable features such as high conductivity, high surface area, excellent chemical endurance, and good mechanical durability. On the other hand, characteristics such as docility, lower price, and high environmental resistance are some of the unique properties of conducting polymers (CPs). To enhance the properties and performance, polymeric electrode materials can be modified suitably by metal oxides and carbon materials resulting in a composite that helps in the collection and accumulation of charges due to large surface area. The carbon-polymer nanocomposites assist in overcoming the difficulties arising in achieving the high performance of polymeric compounds and deliver high-performance composites that can be used in electrochemical energy storage devices. Carbon-based polymer nanocomposites have both advantages and disadvantages, so in this review, attempts are made to understand their synergistic behavior and resulting performance. The three electrochemical energy storage systems and the type of electrode materials used for them have been studied here in this article and some aspects for example morphology, exterior area, temperature, and approaches have been observed to influence the activity of electrochemical methods. This review article evaluates and compiles reported data to present a significant and extensive summary of the state of the art.
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    Cellulose-based smart materials: Novel synthesis techniques, properties, and applications in energy storage and conversion devices
    (Wiley, 2024-05-25) Bishnoi, Pariksha; Siwal, Samarjeet Singh; Kumar, Vinod; Thakur, Vijay Kumar
    There has been a significant scope toward the cutting-edge investigations in hierarchical carbon nanostructured electrodes originating from cellulosic materials, such as cellulose nanofibers, available from natural cellulose and bacterial cellulose. Elements of energy storage systems (ESSs) are typically established upon inorganic/metal mixtures, carbonaceous implications, and petroleum-derived hydrocarbon chemicals. However, these conventional substances may need help fulfilling the ever-increasing needs of ESSs. Nanocellulose has grown significantly as an impressive 1D element due to its natural availability, eco-friendliness, recyclability, structural identity, simple transformation, and dimensional durability. Here, in this review article, we have discussed the role and overview of cellulose-based hydrogels in ESSs. Additionally, the extraction sources and solvents used for dissolution have been discussed in detail. Finally, the properties (such as self-healing, transparency, strength and swelling behavior), and applications (such as flexible batteries, fuel cells, solar cells, flexible supercapacitors and carbon-based derived from cellulose) in energy storage devices and conclusion with existing challenges have been updated with recent findings.
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    Deep eutectic solvents toward the detection and extraction of neurotransmitters: an emerging paradigm for biomedical applications
    (American Chemical Society, 2023-05-17) Kaur, Harjot; Siwal, Samarjeet Singh; Kumar, Vinod; Thakur, Vijay Kumar
    Neurotransmitters (NTs), the chemical messengers crucial for the proper functioning of the human brain, have some specific concentration within the human physiological system. Any fluctuations in their concentration may cause several neuronal diseases and disorders. Therefore, the requirement for fast and effective diagnosis to regulate and manage human cerebral diseases or conditions is surging swiftly. NTs can be extracted from natural products. The researchers have developed new protocols to improve the sensors’ sensing ability and eco-friendly nature. Deep eutectic solvents (DESs) have gained popularity as “green solvents” in sustainable chemistry. DESs provide a greater range of a potential window that helps in the enhanced electrocatalytic performance of the sensor and more inertness which helps in the corrosion protection of electrodes, ultimately giving better sensitivity and durability to the system. In addition, DESs provide facile electrodeposition of different materials on working electrodes, which is a prime prerequisite in electrocatalytic sensors. Here, in this review, the application of DESs as green solvents in detecting and extracting NTs is described in detail for the first time. We cover the available online articles up to December 2022 for the extraction and monitoring of NTs. Finally, we have concluded the topic with future prospects in this field.
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    Energy production from steam gasification processes and parameters that contemplate in biomass gasifier - a review
    (Elsevier, 2019-11-26) Siwal, Samarjeet Singh; Zhang, Qibo; Sun, Changbin; Thakur, Sourbh; Gupta, Vijai Kumar; Thakur, Vijay Kumar
    The transformation of biomass using steam gasification is a chemical route to facilitate changes in organic or residue supported carbonaceous substances addicted to carbon mono-oxide, hydrogen including carbon-di-oxide, etc. However, to commercialize the method of steam gasification, the hurdles persist during the gasification as well as downstream processing. This article delivers a summary of the different approaches that are described in the previous studies to achieve H2 refinement and adaptation within the gasifier system. These include advanced aspects in the research and development of biomass gasification (alike advancements under the gasification operation). The upshot of diverse operating conditions like steam flow rate, operating temperature, moisture content, gasifier agents, residence time, biomass to air, steam to biomass, equivalence ratio, etc. towards the execution of biomass gasifier. This review accomplishes that the interdependence of several issues must be considered in point to optimise the producer gas.
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    Graphitic carbon nitride doped copper–manganese alloy as high–performance electrode material in supercapacitor for energy storage
    (MDPI, 2019-12-18) Siwal, Samarjeet Singh; Zhang, Qibo; Sun, Changbin; Thakur, Vijay Kumar
    Here, we report the synthesis of copper–manganese alloy (CuMnO2) using graphitic carbon nitride (gCN) as a novel support material. The successful formation of CuMnO2-gCN was confirmed through spectroscopic, optical, and other characterization techniques. We have applied this catalyst as the energy storage material in the alkaline media and it has shown good catalytic behavior in supercapacitor applications. The CuMnO2-gCN demonstrates outstanding electrocapacitive performance, having high capacitance (817.85 A·g−1) and well-cycling stability (1000 cycles) when used as a working electrode material for supercapacitor applications. For comparison, we have also used the gCN and Cu2O-gCN for supercapacitor applications. This study proposes a simple path for the extensive construction of self-attaining double metal alloy with control size and uniformity in high-performance energy-storing materials
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    Recent advances in bio-electrochemical system analysis in biorefineries
    (Elsevier, 2021-07-02) Siwal, Samarjeet Singh; Zhang, Qibo; Saini, Adesh Kumar; Gupta, Vijai Kumar; Roberts, Dave; Saini, Vipin; Coulon, Frederic; Pareek, Bhawna; Thakur, Vijay Kumar
    Concerns around acquiring the appropriate resources toward a growing world population have emphasized the significance of crucial connections between food, energy, and water devices, as described within the food-energy-water nexus theory. Advanced biorefineries provide second-generation biofuels and added-value chemicals through food products have affected these nexus sources. We combine various conversion technologies and expected options to look further for cost-effective technologies that maximize the value of resource use and reuse and minimize the amount of resource needed and environmental impacts. In this review article, our central focus is on structure and application, the outline of food-energy-water (FEW) nexus in biorefineries and bio-electrochemical system (BES) and looking into the energy-efficient and value-added product recovery. In addition, based on BES analysis for energy efficiency and valuable product recoveries such as hydrogen evaluation, acetate, recovery of heavy metals, nutrient’s recovery has been discussed under this article. Additionally, we focused on wastewater processing methods, novel electrode materials used in BES, BESs-based desalination and wastewater treatment, recent BES architecture and designs, genetic engineering for enhanced productivity, and valuable materials production surfactants and hydrogen peroxide. Finally, we concluded the topic by discussing the remediation of soil contamination, photosynthetic & microfluidic BES systems, possibilities of employing CO2, including prospects and challenges.