In-situ structural identification of Zr3Al2 type metastable phase during crystallization of a Zr-based MG

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Xing, Yan
Li, Yan
Wang, Xiangke
Yu, Xiangtian
Zhang, Tao
Georgarakis, Konstantinos

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0022-3093

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Yan Xing, Yan Li, Xiangke Wang, Xiangtian Yu, Tao Zhang, Konstantinos Georgarakis, In-situ structural identification of Zr3Al2 type metastable phase during crystallization of a Zr-based MG, Journal of Non-Crystalline Solids, Volume 452, 15 November 2016, pp30-34

Abstract

A metastable phase was detected using higher energy synchrotron radiation when Zr-based metallic glass (MG) was annealed under vacuum in Linkam hot stage at 848 K. The formation and transformation processes of metastable phase were recorded by synchrotron radiation method. The metastable phase during crystallization was identified as Zr3Al2 structure type according to powder diffraction and TEM analysis. The structure of Zr3Al2 type MCP was experimentally evidenced by 3D diffraction patterns and mathematically described. The identification of Zr3Al2 MCP could be helpful for the understanding of cluster structure of MG.

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Github

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Metallic glass, Metastable phase, Crystallization, Synchrotron radiation

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Attribution-NonCommercial-NoDerivatives 4.0 International

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