Gas physisorption measurements as a quality control tool for the properties of graphene/graphite powders

Simple item page
dc.contributor.authorMarchesini, Sofia
dc.contributor.authorTurner, Piers
dc.contributor.authorPaton, Keith R.
dc.contributor.authorReed, Benjamen P.
dc.contributor.authorBrennan, Barry
dc.contributor.authorKoziol, Krzysztof K. K.
dc.contributor.authorPollard, Andrew J.
dc.date.accessioned2020-10-12T10:41:26Z
dc.date.available2020-10-12T10:41:26Z
dc.date.freetoread2021-06-09
dc.date.issued2020-06-08
dc.description.abstractThe industrial-scale production and commercialisation of graphene and related 2D materials introduces the need for rapid, reliable and cost-effective quality control procedures. Currently, microscopy-based techniques are used to measure the lateral size and thickness of particles but while powerful, these techniques suffer from limitations such as lengthy analysis time, high costs and limited sampling. In the case of carbon-based 2D materials, as the stacking of multiple graphene sheets causes a reduction in the surface to mass ratio, the number of layers can hypothetically be calculated by comparing the theoretical surface area of monolayer graphene (2630 m2/g) to the calculated specific surface area (SSA) measured by gas physisorption measurements. However, despite the potential of this method of analysis, there is limited understanding regarding the characterisation of commercial graphene/graphite powders produced via bottom-up and top-down methods. Herein, the SSAs of a variety of commercially-available graphitic powders were measured using nitrogen physisorption isotherms at 77 K and applying Brunauer-Emmett-Teller theory. The as-obtained SSAs were then correlated to the structural and chemical properties of the materials (obtained using conventional techniques) to demonstrate the suitability of this measurement technique for quality control of graphitic powdersen_UK
dc.identifier.citationMarchesini S, Turner P, Paton KR, et al., (2020) Gas physisorption measurements as a quality control tool for the properties of graphene/graphite powders. Carbon, Volume 167, October 2020, pp. 585-595en_UK
dc.identifier.cris27526649
dc.identifier.issn0008-6223
dc.identifier.urihttps://doi.org/10.1016/j.carbon.2020.05.083
dc.identifier.urihttps://dspace.lib.cranfield.ac.uk/handle/1826/15873
dc.language.isoenen_UK
dc.publisherElsevieren_UK
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectSpecific surface areaen_UK
dc.subjectNitrogen physisorptionen_UK
dc.subjectLayersen_UK
dc.subject2D materialsen_UK
dc.subjectGrapheneen_UK
dc.titleGas physisorption measurements as a quality control tool for the properties of graphene/graphite powdersen_UK
dc.typeArticleen_UK

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Gas_physisorption_measurements_as_a_quality_control_tool-2020.pdf
Size:
1.13 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Staff publications (SATM)