Microwave-assisted rapid preparation of hollow carbon nanospheres@TiN nanoparticles for lithium-sulfur batteries
dc.contributor.author | Tu, Jianxin | |
dc.contributor.author | Li, HeJun | |
dc.contributor.author | Zou, Jizhao | |
dc.contributor.author | Zeng, Shao-Zhong | |
dc.contributor.author | Zhang, Qi | |
dc.contributor.author | Yu, Liang | |
dc.contributor.author | Zenga, Xierong | |
dc.date.accessioned | 2019-04-15T11:06:36Z | |
dc.date.available | 2019-04-15T11:06:36Z | |
dc.date.issued | 2018-11-02 | |
dc.description.abstract | Highly conductive titanium nitride (TiN) has a strong anchoring ability for lithium polysulfides (LiPSs). However, the complexity and high cost of fabrication limit their practical applications. Herein, a typical structure of hollow carbon nanospheres@TiN nanoparticles (HCNs@TiN) was designed and successfully synthesized via a microwave reduction method with the advantages of economy and efficiency. With unique structural and outstanding functional behavior, HCN@TiN-S hybrid electrodes display not only a high initial discharge capacity of 1097.8 mA h g−1 at 0.1C, but also excellent rate performance and cycling stability. After 200 cycles, a reversible capacity of 812.6 mA h g−1 is still retained, corresponding to 74% capacity retention of the original capacity and 0.13% decay rate per cycle, which are much better than those of HCNs-S electrodes. | en_UK |
dc.identifier.citation | Jianxin Tu, HeJun Li, JiZhao Zou, et al., (2018) Microwave-assisted rapid preparation of hollow carbon nanospheres@TiN nanoparticles for lithium-sulfur batteries. Dalton Transactions, Volume 47, December 2018, pp. 16909-16917 | en_UK |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | https://doi.org/10.1039/C8DT04095H | |
dc.identifier.uri | https://dspace.lib.cranfield.ac.uk/handle/1826/14081 | |
dc.language.iso | en | en_UK |
dc.publisher | Royal Society of Chemistry | en_UK |
dc.rights | Attribution-NonCommercial 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | * |
dc.title | Microwave-assisted rapid preparation of hollow carbon nanospheres@TiN nanoparticles for lithium-sulfur batteries | en_UK |
dc.type | Article | en_UK |
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