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The effect of uncertainty in predictions of nutrient concentrations from soil spectra on variable-rate fertilizer applications

dc.contributor.authorBreure, Timo S.
dc.contributor.authorWebster, Richard
dc.contributor.authorHaefele, Stephan M.
dc.contributor.authorHannam, Jacqueline A.
dc.contributor.authorCorstanje, Ronald
dc.contributor.authorMilne, Alice E.
dc.date.accessioned2025-10-28T16:13:08Z
dc.date.available2025-10-28T16:13:08Z
dc.date.freetoread2025-10-28
dc.date.issued2025-10-01
dc.date.pubOnline2025-10-06
dc.description.abstractThe concentrations of available phosphorus (P) and potassium (K) in soil can be estimated by soil spectroscopy, and with sufficient sampling can be mapped to guide farmers to apply fertilizer at variable rates. Mapping errors arise from both spatial variation and calibration of the spectra against chemically determined concentrations. We aimed to develop a loss-function framework to explore how sizes of sample sets and calibration sets affect the likely profitability of variable-rate applications of P and K fertilizers. We demonstrate the approach through simulation. Based on our previous observations of variation in P and K from four fields in Cambridgeshire, England, we generated 100 realizations of P and K in each field using geostatistical simulation. We did so with various combinations of sizes of total sample and calibration set. For each such sample we assigned various proportions for calibration on which notionally both soil spectroscopy and chemical concentrations were determined. Knowing the costs for labour in the field for sampling, the preparation of soil in the laboratory, the spectroscopy, chemical analysis and amortization of equipment, we estimated the costs of acquiring data. Set against these were the costs of error, i.e. of uncertainty, in the final predictions by kriging arising from calibration error and spatial variation. For each combination we computed the fertilizer required to minimize the expected loss associated with predictions, where the expected loss is the difference in profit between applying fertilizer for the estimated concentrations of P and K and their true concentrations. The size of the calibration set outweighed the effect of total sample size on the uncertainty associated with predictions. Equally, for the same size of calibration set, there were large differences in the kriging variances between total sample sizes. When the costs of acquiring data were disregarded, the expected loss for available P was strongly affected by the total sample size. For available K, the effect of the size of the calibration sample dominated the expected loss. The expected loss showed diminishing returns with increasing sample size. None of the sample sizes considered would result in a financial gain: spectroscopy needs to become cheaper for it to be cost-effective for variable-rate applications of P and K fertilizer.
dc.description.journalNameGeoderma
dc.description.sponsorshipFunding was provided by Biotechnology and Biological Sciences Research Council (Grant Nos. BBS/E/C/000I0320, BBS/E/C/000I0330, BBS/E/C/000I0100).
dc.identifier.citationBreure TS, Webster R, Haefele SM, et al., (2025) The effect of uncertainty in predictions of nutrient concentrations from soil spectra on variable-rate fertilizer applications. Geoderma, Volume 462, October 2025, Article number 117504en_UK
dc.identifier.elementsID865806
dc.identifier.issn0016-7061
dc.identifier.paperNo117504
dc.identifier.urihttps://doi.org/10.1016/j.geoderma.2025.117504
dc.identifier.urihttps://dspace.lib.cranfield.ac.uk/handle/1826/24579
dc.identifier.volumeNo462
dc.languageEnglish
dc.language.isoen
dc.publisherElsevieren_UK
dc.publisher.urihttps://www.sciencedirect.com/science/article/pii/S0016706125003453?via%3Dihub
dc.rightsAttribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject41 Environmental Sciencesen_UK
dc.subject4106 Soil Sciencesen_UK
dc.subject2 Zero Hungeren_UK
dc.subjectAgronomy & Agricultureen_UK
dc.subjectPrecision agricultureen_UK
dc.subjectProximal soil-sensingen_UK
dc.subjectSoil spectroscopy zen_UK
dc.subjectX-ray fluorescenceen_UK
dc.subjectGeostatisticsen_UK
dc.subjectSimulationen_UK
dc.titleThe effect of uncertainty in predictions of nutrient concentrations from soil spectra on variable-rate fertilizer applicationsen_UK
dc.typeArticle
dc.type.subtypeJournal Article
dcterms.dateAccepted2025-09-04

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