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Item Open Access Silvoarable agroforestry(The Royal Scottish Forestry Society, 1999-01-01) Beaton, A.; Incoll, L. D.; Burgess, Paul J.Introduction: A silvoarable system of land management implies the cultivation of trees and arable crops on the same area of land, a system practised quite commonly in southern Europe and in the tropics. The system comprises two components: tree rows, generally one tree wide, and arable alleys, alternating across the field. The first major development of silvoarable practice in the UK took place during the 1960s and 1970s when Bryant & May established extensive poplar plantations on lowland farmland in southern England to supply their own market for match veneer timber (Beaton, 1987). Since the demise of the Bryant Sr May market for match timber in 1978, interest in the potential for silvoarable systems lay dormant until the advent of food crop surpluses in the 1980s.Item Open Access Intelligent imaging systems for automotive applications(SPIE, 2003-03-31) Thompson, Chris; Huang, Yingping; Fu, ShanIn common with many other application areas, visual signals are becoming an increasingly important information source for many automotive applications. For several years CCD cameras have been used as research tools for a range of automotive applications. Infrared cameras, RADAR and LIDAR are other types of imaging sensors that have also been widely investigated for use in cars. This paper will describe work in this field performed in C2VIP over the last decade - starting with Night Vision Systems and looking at various other Advanced Driver Assistance Systems. Emerging from this experience, we make the following observations which are crucial for "intelligent" imaging systems: 1. Careful arrangement of sensor array. 2. Dynamic-Self-Calibration. 3. Networking and processing. 4. Fusion with other imaging sensors, both at the image level and the feature level, provides much more flexibility and reliability in complex situations. We will discuss how these problems can be addressed and what are the outstanding issues.Item Open Access Report of Committee III.2: fatigue and fracture(Elsevier, 2003-12-31) Brennan, Feargal P.COMMITTEE MANDATE Concern for crack initiation and growth under cyclic loading as well as unstable crack propagation and tearing in ship and offshore structures. Due attention shall be paid to practical application and statistical description of fracture control methods in design, fabrication and service. Consideration is to be given to the suitability and uncertainty of physical models. The work shall be coordinated with that of Committee V.2.Item Open Access Difficulties in using spectral properties to map irrigated areas in a temperate climate: A case study of potatoes in England(2008) Shamal, S.; Weatherhead, E. K.; Knox, Jerry W.Irrigation in England is supplemental to rainfall and only used on a small proportion of the cultivated land, notably on high value vegetable and potato crops. However, it is a significant water user as most of the irrigated area is located in the driest part of England. The existing data on irrigated areas are based on government and industry surveys. Recently these datasets have been used with Geographic Information Systems (GIS) to produce irrigated maps, but these can only be published at catchment level due to confidentiality constraints on the datasets. To assess the possibility of using remote sensing data for mapping the irrigated area, one Landsat image for the summer 2003 was used to compare the spectral signature between irrigated and non-irrigated potato fields in the East of England. ISODATA algorithm was used to perform unsupervised classification, and 50 spectral classes were created. A ground truth dataset was then used to identify the most representative spectral class for irrigated and nonirrigated fields. The result showed that categories both fall into the same spectral class, suggesting there are no significant differences between their spectral properties. Therefore, using satellite imagery may not yet be an appropriate method or need more research for mapping irrigated area in temperate climates such as England. The summer rainfall reduces the water stress differences between irrigated and non-irrigated potato fields such that these satellite sensors cannot yet differentiate the crops.Item Open Access Survey and monitoring of opium poppy and wheat in Afghanistan: 2003-2009(2010-04-01) Taylor, John C.; Waine, Toby W.; Juniper, Graham R.; Simms, Daniel M.; Brewer, Timothy R.An integrated application of remote-sensing technology was devised and applied in Afghanistan during 2003–2009 providing critical information on cereal and poppy cultivation and poppy eradication. The results influenced UK and international policy and counter-narcotics actions in Afghanistan.Item Open Access Neural predictive control of broiler chicken growth(Elsevier, 2010-12-31) Demmers, Theo G. M.; Cao, Yi; Gauss, Sophie; Lowe, John C.; Parsons, David J.; Wathes, Christopher M.Active control of the growth of broiler chickens has potential benefits for farmers in terms of improved production efficiency, as well as for animal welfare in terms of improved leg health. In this work, a differential recurrent neural network (DRNN) was identified from experimental data to represent broiler chicken growth using a recently developed nonlinear system identification algorithm. The DRNN model was then used as the internal model for nonlinear model predicative control (NMPC) to achieve a group of desired growth curves. The experimental results demonstrated that the DRNN model captured the underlying dynamics of the broiler growth process reasonably well. The DRNN based NMPC was able to specify feed intakes in real time so that the broiler weights accurately followed the desired growth curves ranging from $-12%$ to +12% of the standard curve. The overall mean relative error between the desired and achieved broiler weight was 1.8% for the period from day 12 to day 51.Item Open Access An investigation of irregular crack path effects on fracture mechanics parameters using a grain microstructure meshing technique(World Scientific Publishing, 2012-02-02) Mehmanparast, Ali; Biglari, F.; Davies, C. M.; Nikbin, Kamran;A sub-grain size finite element modelling approach is presented in this paper to investigate variations in fracture mechanics parameters for irregular crack paths. The results can be used when modelling intergranular and transgranular crack growth where creep and fatigue are the dominant failure mechanisms and their crack paths are irregular. A novel method for sub-grain scale finite element mesh consisting of multiple elements encased in ~50–150 μm-sized grains has been developed and implemented in a compact tension, C(T), mesh structure. The replicated shapes and dimensions were derived from an isotropic metallic grain structure using representative random sized grain shapes repeated in sequence ahead of the crack tip. In this way the effects of crack tip angle ahead of the main crack path can be considered in a more realistic manner. A comprehensive sensitivity analysis has been performed for elastic and elastic-plastic materials using ABAQUS and the stress distributions, the stress intensity factor and the J-integral have been evaluated for irregular crack paths and compared to those of obtained from analytical solutions. To examine the local and macroscopic graph path effects on fracture mechanics parameters, a few extreme cases with various crack-tip angles have been modelled by keeping the macroscopic crack path parallel to the axis of symmetry. The numerical solutions from these granular mesh structures have been found in relatively good agreement with analytical solutions.Item Open Access Avocado firmness monitoring with values obtained by means of laser doppler vibrometry(International Society for Horticultural Science, 2012-04-01) Terry, Leon A; Landahl, SandraAvocado (Persea americana Mill.) ripeness is usually evaluated by destructive firmness assessment, yet quality is notorious for being heterogeneous within a consignment. This problem, which is especially true for imported avocado fruit, lends itself to searching for non-destructive methods for firmness evaluation. Firmness of objects can be analysed by impulse-response. This technique utilizes recording of a vibration signature and interpretation of the resonant frequency. In this study a laser Doppler vibrometer (LDV) was used for non-contact recording. The aim of this study was to show the feasibility of using a LDV to monitor avocado firmness. In order to create avocado batches of different homogeneity, three groups were treated with and without ethylene, inside or outside a box. After day 0 a third of the fruit were transferred into boxes (325 L) to be treated with ethylene for 24 h. A third was kept in boxes untreated and another third was kept on open trays. Avocado fruit cultivar ‘Hass’ were ripened at 18°C and measured on days 0, 2, 3, 4 and 6. Individual fruit were impacted once and two LDV measurements were taken simultaneously at the stem-end and seed-end. This was repeated twice around the fruit. Force-deformation measurements in compression mode were performed by means of uniaxial testing (Instron model 5542) on two opposite sides (day 0 n=8, then n=24 i.e., 8 per treatment/d). Significant differences were found between firmness of avocados over time and across treatments. Firmness decreased exponentially as expected (304.1 to 2.1 N) over six days. The LDV results showed significant differences between days, treatments and laser-location. The resonant frequency of the fruit decreased linearly until day 4 and then decreased more slowly (1671 to 476 Hz). On average, the frequency found at the seed-end of the fruit was higher than the resonant frequency at the stem-end. This is thought to be due to the seed itself, which could influence the vibration pattern. Resonant frequencies showed good correlation to the logarithm of firmness (r=0.87) and therefore were shown capable of monitoring avocado firmness.Item Open Access Priorities for sustainable turfgrass management: a research and industry perspective(Taylor and Francis, 2012-05-24) Strandberg, M.; Blombäck, K.; Dahl Jensen, A. M.; Knox, Jerry W.This paper provides a brief review and assessment of the key environmental, regulatory and technical issues facing the turfgrass sector with specific reference to the European context. It considers the range of externalities or ‘drivers for change' facing the industry, and the challenges and opportunities available for promoting and achieving more sustainable turfgrass management within the sports, landscape and amenity sectors. The analysis confirms that there are a number of key areas where a concerted research and industrial effort is required. These include responding to the pressures from government demands for greater environmental regulation, the increasing pressure on natural resources (notably water, energy and land), the emerging role of turf management in supporting ecosystem services and enhancing biodiversity, the continued need to promote integrated pest management, and the looming challenges posed by a changing climate, and urgent need to adapt. Whilst many of these externalities appear to be risks to the sports turf industry, there will also be significant opportunities, for those where the labour, energy and agronomic costs are minimized and where the drive to adopt a multifunctional approach to sportsturf management is embraced.Item Open Access Blade design optimisation for fixed-pitch fixed-speed wind turbines(Hindawi Publishing Corporation, 2012-07) Wang, Lin; Tang, Xinzi; Liu, XiongweiFixed-pitch fixed-speed (FPFS) wind turbines have some distinct advantages over other topologies for small wind turbines, particularly for low wind speed sites. The blade design of FPFS wind turbines is fundamentally different to fixed-pitch variable-speed wind turbine blade design. Theoretically, it is difficult to obtain a global mathematical solution for the blade design optimisation. Through case studies of a given baseline wind turbine and its blade airfoil, this paper aims to demonstrate a practical method for optimum blade design of FPFS small wind turbines. The optimum blade design is based on the aerodynamic characteristics of the airfoil, that is, the lift and drag coefficients, and the annual mean wind speed. The design parameters for the blade optimisation include design wind speed, design tip speed ratio, and design attack angle. A series of design case studies using various design parameters are investigated for the wind turbine blade design. The design outcomes are analyzed and compared to each other against power performance of the rotor and annual energy production. The design outcomes from the limited design cases demonstrate clearly which blade design provides the best performance. This approach can be used for any practice of FPFS wind turbine blade design and refurbishment.Item Open Access Prediction of ‘Nules Clementine’ mandarin susceptibility to rind breakdown disorder using Vis/NIR spectroscopy(Elsevier, 2012-07-15) Magwaza, Lembe Samukelo; Opara, Umezuruike Linus; Terry, Leon A.; Landahl, Sandra; Cronje, Paul J.; Nieuwoudt, Helene; Mouazen, Abdul Mounem; Saeys, Wouter; Nicolai, Bart M.The use of diffuse reflectance visible and near infrared (Vis/NIR) spectroscopy was explored as a non-destructive technique to predict ‘Nules Clementine’ mandarin fruit susceptibility to rind breakdown (RBD) disorder by detecting rind physico-chemical properties of 80 intact fruit harvested from different canopy positions. Vis/NIR spectra were obtained using a LabSpec® spectrophotometer. Reference physico-chemical data of the fruit were obtained after 8 weeks of storage at 8 °C using conventional methods and included RBD, hue angle, colour index, mass loss, rind dry matter, as well as carbohydrates (sucrose, glucose, fructose, total carbohydrates), and total phenolic acid concentrations. Principal component analysis (PCA) was applied to analyse spectral data to identify clusters in the PCA score plots and outliers. Partial least squares (PLS) regression was applied to spectral data after PCA to develop prediction models for each quality attribute. The spectra were subjected to a test set validation by dividing the data into calibration (n = 48) and test validation (n = 32) sets. An extra set of 40 fruit harvested from a different part of the orchard was used for external validation. PLS-discriminant analysis (PLS-DA) models were developed to sort fruit based on canopy position and RBD susceptibility. Fruit position within the canopy had a significant influence on rind biochemical properties. Outside fruit had higher rind carbohydrates, phenolic acids and dry matter content and lower RBD index than inside fruit. The data distribution in the PCA and PLS-DA models displayed four clusters that could easily be identified. These clusters allowed distinction between fruit from different preharvest treatments. NIR calibration and validation results demonstrated that colour index, dry matter, total carbohydrates and mass loss were predicted with significant accuracy, with residual predictive deviation (RPD) for prediction of 3.83, 3.58, 3.15 and 2.61, respectively. The good correlation between spectral information and carbohydrate content demonstrated the potential of Vis/NIR as a non-destructive tool to predict fruit susceptibility to RBD.Item Open Access Indicators of soil quality - Physical properties (SP1611). Final report to Defra(Defra, 2012-09-30) Rickson, R. Jane; Deeks, Lynda K.; Corstanje, Ronald; Newell-Price, Paul; Kibblewhite, Mark G.; Chambers, B.; Bellamy, Patricia; Holman, Ian P.; James, I. T.; Jones, Robert; Kechavarsi, C.; Mouazen, Abdul; Ritz, K.; Waine, TobyThe condition of soil determines its ability to carry out diverse and essential functions that support human health and wellbeing. These functions (or ecosystem goods and services) include producing food, storing water, carbon and nutrients, protecting our buried cultural heritage and providing a habitat for flora and fauna. Therefore, it is important to know the condition or quality of soil and how this changes over space and time in response to natural factors (such as changing weather patterns) or to land management practices. Meaningful soil quality indicators (SQIs), based on physical, biological or chemical soil properties are needed for the successful implementation of a soil monitoring programme in England and Wales. Soil monitoring can provide decision makers with important data to target, implement and evaluate policies aimed at safeguarding UK soil resources. Indeed, the absence of agreed and well-defined SQIs is likely to be a barrier to the development of soil protection policy and its subsequent implementation. This project assessed whether physical soil properties can be used to indicate the quality of soil in terms of its capacity to deliver ecosystem goods and services. The 22 direct (e.g. bulk density) and 4 indirect (e.g. catchment hydrograph) physical SQIs defined by Loveland and Thompson (2002) and subsequently evaluated by Merrington et al. (2006), were re-visited in the light of new scientific evidence, recent policy drivers and developments in sampling techniques and monitoring methodologies (Work Package 1). The culmination of these efforts resulted in 38 direct and 4 indirect soil physical properties being identified as potential SQIs. Based on the gathered evidence, a ‘logical sieve’ was used to assess the relative strengths, weaknesses and suitability of each potential physical SQI for national scale soil monitoring. Each soil physical property was scored in terms of: soil function – does the candidate SQI reflect all soil function(s)? land use - does the candidate SQI apply to all land uses found nationally? soil degradation - can the candidate SQI express soil degradation processes? does the candidate SQI meet the challenge criteria used by Merrington et al. (2006)?This approach enabled a consistent synthesis of available information and the semi-objective, semi-quantitative and transparent assessment of indicators against a series of scientific and technical criteria (Ritz et al., 2009; Black et al., 2008). The logical sieve was shown to be a flexible decision-support tool to assist a range of stakeholders with different agenda in formulating a prioritised list of potential physical SQIs. This was explored further by members of the soil science and soils policy community at a project workshop. By emphasising the current key policy-related soil functions (i.e. provisioning and regulating), the logical sieve was used to generate scores which were then ranked to identify the most qualified SQIs. The process selected 18 candidate physical SQIs. This list was further filtered to move from the ‘narrative’ to a more ‘numerical’ approach, in order to test the robustness of the candidate SQIs through statistical analysis and modelling (Work Package 2). The remaining 7 physical SQIs were: depth of soil; soil water retention characteristics; packing density; visual soil assessment / evaluation; rate of erosion; sealing; and aggregate stability. For these SQIs to be included in a robust national soil monitoring programme, we investigated the uncertainty in their measurement; the spatial and temporal variability in the indicator as given by observed distributions; and the expected rate of change in the indicator. Whilst a baseline is needed (i.e. the current state of soil), it is the rate of change in soil properties and the implications of that change in terms of soil processes and functioning that are key to effective soil monitoring. Where empirical evidence was available, power analysis was used to understand the variability of indicators as given by the observed distributions. This process determines the ability to detect a particular change in the SQI at a particular confidence level, given the ‘noise’ or variability in the data (i.e. a particular power to detect a change of ‘X’ at a confidence level of ‘Y%’ would require ‘N’ samples). However, the evidence base for analysing the candidate SQIs is poor: data are limited in spatial and temporal extent for England and Wales, in terms of a) the degree (magnitude) of change in the SQI which significantly affects soil processes and functions (i.e. ‘meaningful change’), and b) the change in the SQI that is detectable (i.e. what sample size is needed to detect the meaningful signal from the variability or noise in the signal). This constrains the design and implementation of a scientifically and statistically rigorous and reliable soil monitoring programme. Evidence that is available suggests that what constitutes meaningful change will depend on soil type, current soil state, land use and the soil function under consideration. However, when we tested this by analysing detectable changes in packing density and soil depth (because data were available for these SQIs) over different land covers and soil types, no relationships were found. Schipper and Sparling (2000) identify the challenge: “a standardised methodology may not be appropriate to apply across contrasting soils and land uses. However, it is not practical to optimise sampling and analytical techniques for each soil and land use for extensive sampling on a national scale”. Despite the paucity in data, all seven SQIs have direct relevance to current and likely future soil and environmental policy, because they can be related (qualitatively) to soil processes, soil functions and delivery of ecosystem goods and services. Even so, meaningful and detectable changes in physical SQIs may be out of time with any soil policy change and it is not usually possible to link particular changes in SQIs to particular policy activities. This presents challenges in ascertaining trends that can feed into policy development or be used to gauge the effectiveness of soil protection policies (Work Package 3). Of the seven candidate physical SQIs identified, soil depth and surface sealing are regarded by many as indicators of soil quantity rather than quality. Visual soil evaluation is currently not suited to soil monitoring in the strictest sense, as its semi-qualitative basis cannot be analysed statistically. Also, few data exist on how visual evaluation scores relate to soil functions. However, some studies have begun to investigate how VSE might be moved to a more quantified scale and the method has some potential as a low cost field technique to assess soil condition. Packing density requires data on bulk density and clay content, both of which are highly variable, so compounding the error term associated with this physical SQI. More evidence is needed to show how ‘meaningful’ change in aggregate stability affects soil processes and thus soil functions (for example, using the limited data available, an equivocal relationship was found with water regulation / runoff generation). The analysis of available data has given promising results regarding the prediction of soil water retention characteristics and packing density from relatively easy to measure soil properties (bulk density, texture and organic C) using pedotransfer functions. Expanding the evidence base is possible with the development of rapid, cost-effective techniques such as NIR sensors to measure soil properties. Defra project SP1303 (Brazier et al., 2012) used power analyses to estimate the number of monitoring locations required to detect a statistically significant change in soil erosion rate on cultivated land. However, what constitutes a meaningful change in erosion rates still requires data on the impacts of erosion on soil functions. Priority cannot be given amongst the seven SQIs, because the evidence base for each varies in its robustness and extent. Lack of data (including uncertainty in measurement and variability in observed distributions) applies to individual SQIs; attempts at integrating more than one SQI (including physical, biological and chemical SQIs) to improve associations between soil properties and processes / functions are only likely to propagate errors. Whether existing monitoring programmes can be adapted to incorporate additional measurement of physical SQIs was explored. We considered options where one or more of the candidate physical SQIs might be implemented into soil monitoring programmes (e.g. as a new national monitoring scheme; as part of the Countryside Survey; and as part of the National Soil Inventory). The challenge is to decide whether carrying out soil monitoring that is not statistically robust is still valuable in answering questions regarding current and future soil quality. The relationship between physical (and other) SQIs, soil processes and soil functions is complex, as is how this influences ecosystem services’ delivery. Important gaps remain in even the realisation of a conceptual model for these inter-relationships, let alone their quantification. There is also a question of whether individual quantitative SQIs can be related to ecosystem services, given the number of variables.Item Open Access The implications of a changing climate on agricultural land classification in England and Wales(Cambridge University Press, 2012-10-30) Keay, C. A.; Jones, Robert J. A.; Hannam, Jacqueline A.; Barrie, I. A.The agricultural land classification (ALC) of England and Wales is a formal method of assessing the quality of agricultural land and guiding future land use. It assesses several soil, site and climate criteria and classifies land according to whichever is the most limiting. A common approach is required for calculating the necessary agroclimatic parameters over time in order to determine the effects of changes in the climate on land grading. In the present paper, climatic parameters required by the ALC classification have been re-calculated from a range of primary climate data, available from the Meteorological Office's UKCP09 historical dataset, provided as 5 km rasters for every month from 1914 to 2000. Thirty-year averages of the various agroclimatic properties were created for 1921–50, 1931–60, 1941–70, 1951–80, 1961–90 and 1971–2000. Soil records from the National Soil Inventory on a 5 km grid across England and Wales were used to determine the required soil and site parameters for determining ALC grade. Over the 80-year period it was shown that the overall climate was coolest during 1951–80. However, the area of land estimated in retrospect as ‘best and most versatile (BMV) land’ (Grades 1, 2 and 3a) probably peaked in the 1951–80 period as the cooler climate resulted in fewer droughty soils, more than offsetting the land which was downgraded by the climate being too cold. Overall there has been little change in the proportions of ALC grades among the six periods once all 10 factors (climate, gradient, flooding, texture, depth, stoniness, chemical, soil wetness, droughtiness and erosion) are taken into account. This is because it is rare for changes in climate variables all to point in the same direction in terms of ALC. Thus, a reduction in rainfall could result in higher grades in wetter areas but lead to lower classification in drier areas.Item Open Access Monitoring of renewable energy yield of mixed wastes by image analysis of input residual waste materials(CISA Publisher, 2012-11) Wagland, Stuart Thomas; Longhurst, Philip J.A novel image analysis method has been developed by Cranfield University. Following on from a recent study, this approach has been applied alongside calorific values and %14C to determine the renewable energy content of mixed wastes. This method determines the composition of the mixed waste material, and then using calorific values and biogenic carbon (14C) content the renewable energy potential of the mixed waste sample can be accurately determined. The correlations between actual (known) weights and composition of the components and the values from the image analysis are compared; these correlations (r ≥0.988) were found to be highly significant (p<0.005). The renewable energy contents (as a % of the total energy) were calculated to be between 0.64 and 3.98 below the actual values. Potential applications for the image analysis tool include a) renewable energy potential of mixed wastes prior to combustion, and b) certification of solid recovered fuels [SRF].Item Open Access Safety assessment of novel polymer-silicon composites - from LCA perspective(Publications Office of the European Union, 2012-12) Zhu, Huijun; Irfan, Adeel; Sachse, Sophia; Njuguna, JamesThe fast growing trend in the development of novel materials with potential applications in many industrial sectors has caused concerns over the environment and human health effect of the emerging activities and associated products. It is imperative that these concerns are addressed in a holistic manner as early as possible. As part of the NEPHH project, this study applied the LCA concept aiming to identify hazardous nanoparticles (NP) that could be released during the development and application of novel products, focusing on polymeric-silicon composites in recognition of their attractions to a wide range of industries, including construct engineering, automotive and aerospace.Item Open Access Modeling of a supercritical power plant with an oxy type pulverized fuel boiler, a carbon dioxide capture unit and a ‘four-end’ type membrane air separator(Polish Academy of Sciences, 2012-12-31) Kotowicz, Janusz; Michalski, SebastianThe analysis of a 600 MW supercritical power plant with parameters of life steam at 30 MPa/ /650o C and of reheated steam 6 MPa/670o C was made. Power plant is equipped with the following units: oxy type pulverized fuel boiler, ‘four-end’ high temperature membrane air separator and carbon dioxide capture system which were modeled. With the assumption of a constant gross power of the analyzed power plant, the thermal efficiency of the boiler and the steam cycle efficiency were calculated. These parameters were designated as a function of the recovery rate of oxygen in the air separation unit. This allowed to determine gross and net efficiency of electricity generation.Item Open Access Influence of compost amendments on the hydraulic functioning of brownfield soils(Wiley, 2013-01-21) Whelan, A.; Kechavarzi, C.; Coulon, Frederic; Sakrabani, Ruben; Lord, R.This study assessed the impact of compost on the hydraulic properties of three soils (sandy loam, clay loam and diesel-contaminated sandy loam) with relatively poor physical quality typical of brownfield sites. Soils were amended with two composts at 750 t/ha. Samples were also collected from a clay-capped brownfield site, previously amended with 250, 500 or 750 t/ha of compost. Water-release characteristics and saturated hydraulic conductivity were determined for all soils and physical quality indicators derived. Unsaturated flow in field profiles after compost application with two depths of incorporation and two indigenous subsoils was simulated using Hydrus-1D. Compost generally increased water retention. Hydraulic conductivity tended to decrease following compost application in sandy loam but increased in clay and clay loam, where compost addition resulted in a larger dominant pore size. Although compost improved physical quality indicators, they remained suboptimum in clay and clay loam soil, which exhibited poor aeration, and in the contaminated sandy loam, where available water capacity was limited, possibly due to changes in wettability. Increasing application rates in the field enhanced water retention at low potentials and hydraulic conductivity near saturation but did not alter physical quality indicators. Numerical simulation indicated that the 500 t/ha application resulted in the best soil moisture regime. Increasing the depth of incorporation in the clay cap improved drainage and reduced waterlogging, but incorporation in more permeable subsoil resulted in prolonged dry conditions to greater depths.Item Open Access Characterization of indoor/outdoor settled dust and air pollutants in Damaturu, Nigeria(IJET, 2013-01-25) Mohammed, Fatima S.; Crump, DerrickThis paper presents results of on-going experiments being undertaken to characterise the composition of settled dusts and some airborne contaminants in homes and outdoors in Damaturu, north-eastern Nigeria. These have involved the physical analysis of the dust samples collected from different homes by scanning electron microscopy (SEM) which showed images of particles of 2µm to 50µm and fragmented filamentous particles of 50µm to 200µm. Microbiological analysis conducted include media culture and microscopic observations where a range of fungal and bacterial colonies were identified with colony forming units in settled dust and air of between 1.02 10 4 to1.18 10 5 CFU g -1 and 1.07 10 4 1.69 10 5 CFU m -3 (for fungi)and 7.70 10 3 to1.14 10 5 CFU g -1 , 1.90 10 3 to 1.13 10 5 CFU m -3 (for bacteria) . Metal analysis by ICP-MS (total quant method) of the settled dusts revealed the presence of metal elements in the range of Al>Na>Mg>Ca>K>P>Si>Mn>Ti and indicated the maximum concentration of Lead, Copper, Cadmium, Nickel and Zinc (mg kg -1 ) to bePb-89.7, Cu-68.4, Cd-15.6, Ni-14.9, Zn-1.15.The results also revealed the presence of organic chemical pollutants in varying concentrations in the indoor and outdoor dusts and airborne samples within different homes; eight semi-volatile and volatile organic compounds(SVOCs/VOCs); benzene, hex anal, nonanal, diethyl phthalate (DEP), diisobutylphthalate (DIBP), dibutylphthalate (DBP), and diethylhexylphthalate (DEHP) and limonene were quantified among the numerous organic chemicals present in the samples analysed based on their frequency of occurrence in the samples collected, as well as their potential health effects arising from short term and long term exposure as reported in earlier studies. The results suggested that the indoor environments contain considerably more organic chemical pollutants than the outdoors. From the results obtained so far on the chemical, metal, and biological pollutants present as well as the physical characteristics of indoor dusts from Nigerian homes, it can be ascertained that the dusts act as a reservoir of pollutants that can increase peoples’ exposure and be a risk to the health of residents of the community.Item Open Access Quantifying the loss of methane through secondary gas mass transport (or 'slip') from a micro-porous membrane contactor applied to biogas upgrading(IWA Publishing, 2013-04-29) McLeod, Andrew J.; Jefferson, Bruce; McAdam, Ewan J.Secondary gas transport during the separation of a binary gas with a micro-porous hollow fibre membrane contactor (HMFC) has been studied for biogas upgrading. In this application, the loss or ‘slip' of the secondary gas (methane) during separation is a known concern, specifically since methane possesses the intrinsic calorific value. Deionised (DI) water was initially used as the physical solvent. Under these conditions, carbon dioxide (CO2) and methane (CH4) absorption were dependent upon liquid velocity (VL). Whilst the highest CO2 flux was recorded at high VL, selectivity towards CO2 declined due to low residence times and a diminished gas-side partial pressure, and resulted in slip of approximately 5.2% of the inlet methane. Sodium hydroxide was subsequently used as a comparative chemical absorption solvent. Under these conditions, CO2 mass transfer increased by increasing gas velocity (VG) which is attributed to the excess of reactive hydroxide ions present in the solvent, and the fast conversion of dissolved CO2 to carbonate species reinitiating the concentration gradient at the gas-liquid interface. At high gas velocities, CH4 slip was reduced to 0.1% under chemical conditions. Methane slip is therefore dependent upon whether the process is gas phase or liquid phase controlled, since methane mass transport can be adequately described by Henry's law within both physical and chemical solvents. The addition of an electrolyte was found to further retard CH4 absorption via the salting out effect. However, their applicability to physical solvents is limited since electrolytic concentration similarly impinges upon the solvents' capacity for CO2. This study illustrates the significance of secondary gas mass transport, and furthermore demonstrates that gas-phase controlled systems are recommended where greater selectivity is required,Item Open Access Hydrological modelling using data from monthly GCMs in a regional catchment(Wiley, 2013-05-30) Remesan, Renji; Bellerby, Tim; Frostick, LynneThis study demonstrates the use of spatially downscaled, monthly general circulation model (GCM) rainfall and temperature data to drive the established HyMOD hydrological model to evaluate the prospective effects of climate change on the fluvial run-off of the River Derwent basin in the UK. The evaluation results of this monthly hydrological model using readily available, monthly GCM data are consistent with studies on nearby catchments employing high-temporal resolution data, indicating that useful hydro-climatic planning studies may be possible using standard datasets and modest computational resources. HyMOD was calibrated against 5 km2 gridded UK Climate Projections dataset data and then driven using monthly spatially interpolated (~5 km2) outputs from Hadley Centre Coupled Model, version 3 and the Canadian Centre for Climate Modelling and Analysis for Intergovernmental Panel on Climate Change Special Report on Emissions Scenarios (IPCC-SRES) A2a and B2a covering the 2020s, 2050s and 2080s. Results for both GCMs project a decrease in annual run-off in both GCM models and scenarios with higher values in the summer/autumn months, whereas an increase in the later winter months. Both Hadley Centre Coupled Model, version 3 and the Canadian Centre for Climate Modelling and Analysis show higher ranges of uncertainty during the winter season with higher values of run-off associated with December in all three simulation periods and two scenarios. A seasonal comparison of run-off simulations shows that both GCMs give similar results in summer and autumn, whereas disparities due to GCM uncertainties are more conspicuous in winter and spring. In this study, both the GCMs under A2a scenario have demonstrated the high possibility of time shift in monthly average peak run-offs in the Derwent River by 2080s in comparison with the early 21st century.